★精细化工
同专业博导
曲景平
彭孝军
孙立成
吴祖望
张淑芬
赵伟杰
包明
段春迎
吕荣文
马廷丽
崔京南
具本植
肖义
张晓安
李久艳
杨希川
孙世国
乔卫红
樊江莉
刘春
赵忠奎
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同专业硕导
唐炳涛
李晓莲
周宇涵
王梅(小)
宫国梁
申凯华
马威
张蓉
王忆铭
周新锐
于晓强
宋锋玲
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编辑导师资料
赵建章
院系：
化工学院
办公电话：
0411 8498 6236
电子信箱：
zhaojzh@dlut.edu.cn
更新时间：
2012-9-6
其他专业：
应用化学
化学工程
个人简介
1996-2000年, 吉林大学化学系工作；
2000年, 吉林大学化学系获理学博士学位；
2000-2001年, 韩国国立智能超分子创新研究中心（浦项理工大学），博士后（葫芦脲化学）；
2001-2003年, 德国马普研究所（蛋白质折叠的酶学），博士后（肽的光化学）；
2003-2005年, 英国巴斯大学化学系，高级研究人员(Research Officer。手性荧光分子探针)；
2005年7月起在大连理工大学化工学院工作。
先后获得国家自然科学基金委主任基金以及面上项目 (20634040, 20972024, 21073028，21273028); 教育部新世纪优秀人才支持计划(NCET-08-0077), 教育部博士点基金(200801410004), 英国皇家学会(RS)-NSFC联合资助项目(21011130154), 英国皇家学会(RS)-国家留学基金管理委员会联合资助项目; 瑞士-中国科技合作项目(EG21-092011), 爱尔兰科学基金会E.T.S. Walton访问学者(11/W.1/E2061)等项目的资助。
课题组网址：http://finechem.dlut.edu.cn/photochem
社会兼职
曾为J. Am. Chem. Soc., Angew. Chem. Int. Ed., Adv. Funct. Mater., Acc. Chem. Res., Chem. Eur. J., J. Org. Chem., J. Mater. Chem., Dalton Trans., Chem. Commun., New. J. Chem., J. Phys. Chem. 等期刊审稿80余篇（部分为仲裁审稿人）。此外审理国家自然科学基金申请、博士点基金申请等50余项。
研究领域（研究课题）
本课题组的主要研究方向是分子光化学与光物理，主要从事荧光分子探针和磷光金属配合物的研究。曾研究了基于2,4-二硝基磺酰基的巯基化合物荧光探针，以及用于检测葡萄糖、酒石酸和扁桃酸等的硼酸探针。此外我们还设计并制备具有强可见光吸收能力、长激发态寿命的Ru(II), Pt(II) 和Ir(III) 等过渡金属配合物，这些金属配合物可用于光伏、光催化、光动力治疗等领域。研究结果被Dalton Trans. 选为内封面论文（两篇），被Eur. J. Inorg. Chem. 选为封面论文，被Chem. Comm., PCCP以及J. Mater. Chem.等期刊选为封底论文（Back Cover，共6篇封面、封底论文），部分研究成果已被Nature China、Chem. Eur. J. 进行了专题介绍。国际知名科技网站 Physorg.com和 Esciencenews.com 对我们设计合成的具有强可见光吸收、长三重激发态寿命的配合物的合成和性质研究做了介绍。
研究工作涉及合成化学、光谱测试与应用研究。主要使用各种稳态与瞬态光谱对所制备的化合物的性质进行表征，如紫外-可见吸收光谱，分子荧光以及磷光光谱，低温光谱(77 K), 以及纳秒时间分辨瞬态吸收光谱（激光闪光光解）。此外，我们还系统将理论化学计算（DFT方法）用于化合物光物理性质的研究（如预测发光性质）。所制备的化合物可用于葡萄糖、酒石酸、扁桃酸、半胱氨酸等的检测，以及发光法氧传感、三重态-三重态 湮灭上转换、光动力治疗等。
正在进行的研究工作包括：
1、提出了硼酸荧光探针的d-PET机理。与常见的a-PET机理的硼酸荧光探针不同，在d-PET机理的硼酸探针中，荧光基团做为光诱导电子转移的电子给体。d-PET机理的荧光探针的荧光性质与传统的a-PET探针的性质有很大不同，克服了传统a-PET探针的某些局限、缺点；
2、系统地将理论化学计算应用于荧光探针的研究，预测、解释荧光探针的荧光变化；提出用“态”的概念，而非分子轨道的概念，来解释荧光探针的荧光性质，并已通过实例验证了该概念；
3、提出使用“暗态”的概念来解释荧光探针的荧光开关效应(OFF-ON)。不发光的探针往往具有暗态（通常指S1激发态，S1->S0为禁阻跃迁，为非辐射跃迁），所以无荧光；探针与底物作用后，第一激发态的性质发生变化，S1态转变为发射态（emissive state）, 所以会观察到荧光增强。暗态和发射态的判断依据是DFT计算的结果；
4、初步提出了具有强可见光吸收能力的过渡金属配合物的设计原则，即配体的能级必须与金属配位中心的能级（MLCT激发态）匹配，并已通过实例验证；
5、提出使用具有较长寿命的3IL激发态用于三重态-三重态 湮灭上转换，与传统的MLCT激发态相比，提高了上转换量子效率；此外，我们提出使用具有暗态的配合物进行上转换，而现有的三重态敏化剂大多是发磷光的配合物。实际上敏化剂的磷光对上转换不利。这些新的概念将提高TTA上转换的效率、拓宽三重态敏化剂的选择范围；
6、我们提出使用有机三重态敏化剂取代传统的、价格较贵的过渡金属配合物三重态敏化剂，进行上转换研究，并已通过制备BODIPY衍生得到敏化剂库（library）予以了验证。该敏化剂库的合成，开启了TTA 上转换的三重态敏化剂由金属配合物到有机化合物的转变，与染料敏化太阳能电池（DSCs）中使用的敏化剂的发展所经历的转变类似，但更具挑战性，因为对于TTA上转换的敏化剂来说，敏化剂的三重激发态必须能高效布居，而不是DSCs敏化染料的单重态。目前我们正积极研究新型的纯有机三重态敏化剂。
本课题组有合成化学实验室（共十一个通风橱），以及总价值一百多万元的光谱仪器设备，可进行稳态与瞬态光谱研究，如岛津2550紫外-可见吸收光谱仪、安捷伦8453紫外-可见-近红外吸收光谱仪，岛津RF5301PC荧光光谱仪（红敏检测器）、CRT 970 荧光光谱仪（经改装，适于做氧传感、上转换等研究工作）、牛津Optistat DN低温光学杜瓦（77 K - 300 K，可控变温）、不同输出波长的二极管泵浦固体激光器（DPSSL，5台）、OB 920 荧光/磷光寿命测定仪（Edinburgh Instruments. 可测发光寿命范围ps - s）、用于理论化学计算的双路八核服务器（四台）、Gaussian 09W软件、以及自行组装的一些仪器设备（包括小型化的微秒时间分辨磷光寿命测定仪、发光法氧传感测试用流通池、光氧化反应在线光谱检测装置）等。另外课题组还可使用重点实验室的LP920 纳秒时间分辨瞬态吸收光谱仪（激光闪光光解，Edinburgh Instruments)， 以及FSL 920全功能荧光光谱仪（配备有与仪器同步的OPO纳秒激光器与EPL皮秒激光器）。
在精细化工、应用化学专业招生。
硕博研究方向
分子光化学与光物理（合成化学，稳态与瞬态光谱，理论化学计算，基础应用研究等）。
出版著作和论文
80. Light Harvesting Fullerene Dyads as Organic Triplet Photosensitizers for Triplet-triplet Annihilation Upconversions.
Wanhua Wu, Jianzhang Zhao,* Jifu Sun and Song Guo.
J. Org. Chem., 2012, in press.
79. Visible light-harvesting perylenebisimide–fullerene (C60) dyads with bidirectional ‘‘ping-pong’’ energy transfer as triplet photosensitizers for photooxidation of 1,5 dihydroxynaphthalene.
Yifan Liu and Jianzhang Zhao.*
Chem. Commun., 2012, 48, 3751–3753.
78. Styryl Bodipy-C60 Dyads as Efficient Heavy-Atom-Free Organic Triplet Photosensitizers.
Ling Huang, Xuerong Yu, Wanhua Wu, and Jianzhang Zhao*
Org. Lett., 2012, 14, 2594–2597.
77. Rhenium(I) tricarbonyl polypyridine complexes showing strong absorption of visible light and long-lived triplet excited states as triplet photosensitizer for triplet-triplet annihilation upconversion.
Xiuyu Yi, Jianzhang Zhao,* Wanhua Wu, Dandan Huang, Shaomin Ji and Jifu Sun.
Dalton Trans., 2012, in press.
76. Room Temperature Long-lived Triplet Excited State of Fluorescein in N^N Pt(II)Bisacetylide Complex and Its Applications for Triplet-triplet Annihilation Based Upconversions.
Wenting Wu, Jianzhang Zhao,* Wanhua Wu and Yinghui Chen.
J. Organomet. Chem., 2012, in press.
75. Access to a large stokes shift in functionalized fused coumarin derivatives by increasing the geometry relaxation upon photoexcitation: An experimental and theoretical study.
Dandan Huang, Yinghui Chen, Jianzhang Zhao.*
Dyes and Pigments, 2012, in press.
74. Iridium complexes incorporating coumarin moiety as catalyst photoinitiators:Towards household green LED bulb and halogen lamp irradiation.
Mohamad-Ali Tehfe, Jacques Lalevée,* Sofia Telitel, Jifu Sun, Jianzhang Zhao, Bernadette Graff, Fabrice Morlet-Savary, Jean-Pierre Fouassier.
Polymer, 2012, in press.
73. Efficient Triplet-triplet Annihilation Upconversion with Platinum (II) Bis(arylacetylide) Complexes That Show Long-lived Triplet Excited States.
Shaomin Ji, Wanhua Wu, Jianzhang Zhao,* Huimin Guo, and Wenting Wu.
Eur. J. Inorg. Chem., 2012, DOI: 10.1002/ejic.201200109.
72. Facilitative Functionalization of Cyanine Dye by On-Off-On Fluorescent Switch for Imaging of H2O2 Oxidative Stress and Thiols Reducing Repair in Cells and Tissues.
Fabiao Yu, Peng Li, Ping Song, Bingshuai Wang, Jianzhang Zhao and Keli Han.*
Chem. Commun., 2012, accepted.
71. Long-lived Room Temperature Deep-red Emissive Intraligand Triplet Excited State of Naphthalimide in Cyclometalated Ir(III) Complexes and Its Application in Triplet-triplet Annihilation Based Upconversion.
Jifu Sun, Wanhua Wu and Jianzhang Zhao.*
Chem. Eur. J., 2012, accepted.
70. Room Temperature Long-lived Triplet Excited States of Naphthalenediimides and Their Applications as Organic Triplet Photosensitizers for Photooxidation and Triplet-triplet Annihilation Upconversions.
Song Guo, Wanhua Wu, Huimin Guo, and Jianzhang Zhao.*
J. Org. Chem., 2012, 77, 3933–3943.
69. Thienyl-substituted BODIPYs with strong visible light-absorption and long-lived triplet excited states as organic triplet sensitizers for triplet-triplet annihilation upconversion.
Yinghui Chen, Jianzhang Zhao,* Lijuan Xie, Huimin Guo and Qiuting Li.
RSC Adv., 2012, 2, 3942–3953.
68. Geometry Relaxation-induced Large Stokes Shift in Red-emitting Borondipyrromethenes (BODIPY) and the Applications in Fluorescent Thiol Probes.
Yinghui Chen, Jianzhang Zhao,* Huimin Guo and Lijuan Xie.
J. Org. Chem., 2012, 77, 2192–2206.
Top 20 most downloaded JOC articles for the month of March, 2012. http://pubs.acs.org/action/showMostReadArticlesjournalCode=joceah&topArticlesType=month
67. An ICT-based strategy to a colorimetric and ratiometric fluorescence probe for hydrogen sulfide in living cells.
Fabiao Yu, Peng Li, Ping Song, Bingshuai Wang, Jianzhang Zhao and Keli Han.*
Chem. Commun., 2012, DOI: 10.1039/c2cc17658k.
66. Visible-light harvesting iridium complexes as singlet oxygen sensitizers for photooxidation of 1,5-dihydroxynaphthalene.
Jifu Sun, Jianzhang Zhao,* Huimin Guo and Wanhua Wu.
Chem. Commun., 2012, 48, 4169–4171. Back cover paper.
65. Encapsulation of hydrophobic pyrenylcycloplatinate complexes within a water-soluble arene ruthenium metallacage.
Nicolas P.E. Barry , Olivier Zava, Wenting Wu, Jianzhang Zhao, Bruno Therrien.*
Inorganic Chemistry Communications. 2012, accepted.
64. Selective Saccharide Recognition Using Modular Diboronic Acid Fluorescent Sensors.
Zhitao Xing, Hui-Chen Wang, Yixiang Cheng, Chengjian Zhu,* Tony D. James,* and Jianzhang Zhao.
Eur. J. Org. Chem. 2012, 10.1002/ejoc.201101633.
63. Ruthenium(II) Polyimine-Coumarin Light Harvesting Molecular Arrays: Design Rationales and Application for Triplet-triplet Annihilation Based Upconversion.
Wanhua Wu, Shaomin Ji, Wenting Wu, Jingyin Shao, Huimin Guo, Tony D. James, and Jianzhang Zhao.*
Chem.Eur. J., 2012, 18, 4953 – 4964
62. Tuning the Photophysical Properties of N^N Pt(II) Bisacetylide Complexes with Fluorene Moiety and Its Applications for Triplet-triplet-annihilation based Upconversion.
Qiuting Li, Huimin Guo,* Lihua Ma, Wanhua Wu, Yifan Liu and Jianzhang Zhao.*
J. Mater. Chem., 2012, 22, 5319–5329. Back cover paper.
61. Excited state intramolecular proton transfer (ESIPT): from principal photophysics to the development of new chromophores and applications in fluorescent molecular probes and luminescent materials.
Jianzhang Zhao,* Shaomin Ji, Yinghui Chen, Huimin Guo* and Pei Yang.
Phys. Chem. Chem. Phys., 2012. accepted. Invited Perspective Feature review. Back cover paper.
60. A Highly Selective Red-emitting FRET Fluorescent Molecular Probe Derived From BODIPY for the Detection of Cysteine and Homocysteine: An Experimental and Theoretical Study.
Jingyin Shao, Haiyang Sun, Huimin Guo, Shaomin Ji, Jianzhang Zhao,* Wenting Wu, Xiaolin Yuan, Chunlei Zhang and Tony D. James.*
Chem. Sci., 2012, 3, 1049–1061.
59. Transition Metal Complexes with Strong Absorption of Visible Light and Long-lived Triplet Excited States: From Molecular Design to Applications.
Jianzhang Zhao,* Shaomin Ji, Wanhua Wu, Wenting Wu, Huimin Guo,* Jifu Sun, Haiyang Sun, Yifan Liu, Qiuting Li and Ling Huang.
RSC Adv., 2012, 2, 1712–1728. Review.
58. Long-lived Room Temperature Near-IR Phosphorescence of BODIPY in a Visible light-harvesting N^C^N Pt(II) Acetylide Complex with Directly Metalated BODIPY Chromophore.
Wanhua Wu, Jianzhang Zhao,* Huimin Guo, Jifu Sun, Shaomin Ji and Zilong Wang.
Chem. Eur. J., 2012, 18, 1961 – 1968.
57. BF2-Bound Chromophore-containing N^N Pt(II) Bisacetylide Complex and Its Applications As Sensitizer for Triplet-triplet annihilation Based Upconversion.
Yifan Liu, Qiuting Li, Jianzhang Zhao* and Huimin Guo.*
RSC Adv., 2012, 2, 1061–1067.
56. Fluorescent coumarin derivatives with large stokes shift, dual emission and solid state luminescent properties: An experimental and theoretical study.
Lijuan Xie,* Yinghui Chen, Wenting Wu, Huimin Guo, Jianzhang Zhao,* Xuerong Yu.
Dyes and Pigments., 2012, 92, 1361－1369.
55. Colorimetric and Ratiometric Fluorescent Chemosensor Based on Diketopyrrolopyrrole (DPP) for Selective Detection of Thiols: An Experimental and Theoretical Study.
Ling Deng, Wenting Wu, Huimin Guo, Jianzhang Zhao,* Shaomin Ji, Xin Zhang, Xiaolin Yuan, and Chunlei Zhang.
J. Org. Chem., 2011, 76, 9294-9304.
54. Long-Lived Room Temperature Deep-Red/Near-IR Emissive Intraligand Triplet Excited State (3IL) of Naphthalimide in Cyclometalated Pt(II) Complexes and Its Application in Upconversion.
Wenting Wu, Huimin Guo, Wanhua Wu, Shaomin Ji, and Jianzhang Zhao.*
Inorg. Chem., 2011, 50, 11446-11460.
53. Ratiometric luminescent molecular oxygen sensors based on uni-luminophores of C^N Pt(II)(acac) complexes that show intense visible-light absorption and balanced fluorescence/phosphorescence dual emission.
Yifan Liu, Huimin Guo and Jianzhang Zhao.*
Chem. Commun. 2011, 47, 11471–11473.
52. Triplet–triplet annihilation based upconversion: from triplet sensitizers and triplet acceptors to upconversion quantum yields.
Jianzhang Zhao,* Shaomin Ji and Huimin Guo.
RSC Adv., 2011, 1, 937–950. Review.
51. Tuning the Emissive Triplet Excited States of Platinum(II) Schiff base Complexes with Pyrene, and Application for Luminescent Oxygen Sensing and Triplet–triplet-annihilation Based Upconversions.
Wanhua Wu, Jifu Sun, Shaomin Ji, Wenting Wu, Jianzhang Zhao* and Huimin Guo*
Dalton Trans. 2011, 40, 11550–11561.
50. Room Temperature Long-lived 3IL Excited State of Rhodamine in a N^N Pt(II) Bisacetylide Complex Which Shows Intense Visible Light Absorption.
Ling Huang, Le Zeng, Huimin Guo, Wanhua Wu, Wenting Wu, Shaomin Ji and Jianzhang Zhao*
Eur. J. Inorg. Chem., 2011, 4527–4533.
49. Organic Triplet Sensitizer Library Derived froma Single Chromophore (BODIPY) with Long-Lived Triplet Excited State for Triplet-Triplet Annihilation Based Upconversion.
Wanhua Wu, Huimin Guo, Wenting Wu, Shaomin Ji, and Jianzhang Zhao*
J. Org. Chem., 2011, 76 (17), 7056–7064.
48. Thiophene Inserted Aryl Dicyanovinyls: The Second Generation of Fluorescent Molecular Rotors with Substantially Red-shifted Emission and Large Stokes Shift.
Jingyin Shao, Shaomin Ji, Xiaolian Li, Jianzhang Zhao,* Fuke Zhou and Huimin Guo.*
Eur. J. Org. Chem., 2011, 39, 6100-6109.
47. Ruthenium(II) Polyimine-Coumarin Dyad with Non-emissive 3IL Excited State as Sensitizer for Triplet-Triplet-Annihilation Based Upconversion.
Shaomin Ji, Huimin Guo, Wenting Wu, Wanhua Wu, Jianzhang Zhao.*
Angew. Chem. Int. Ed., 2011, 11, 50, 8283-8286.
46. Visible-light Harvesting Cyclometalated Iridium (III) Complexes with Long-lived 3IL Excited States and Their Application for Triplet-triplet-annihilation Based Upconversions.
Jifu Sun, Wanhua Wu, Huimin Guo and Jianzhang Zhao.*
Eur. J. Inorg. Chem., 2011, 3165–3173. Front cover paper.
Highlighted by www.physorg.com and esciencenews.com
For detail, please refer to http://www.phyorg.com/news/2011-06-visible-energy-harvesting.html and http://esciencenews.com/sources/physorg/2011/06/23/learning.plants.visible.light.energy.harvesting
45. Enantioselective Recognition of Mandelic Acid by a 3,6-Dithiophen-2-yl-9H-carbazole Based Chiral Fluorescent Bisboronic Acid Sensor.
Yubo Wu, Huimin Guo, Tony D. James and Jianzhang Zhao.*
J. Org. Chem., 2011, 2011, 76, 5685–5695
44. Ruthenium(II) Polyimine Complexes with a Long-Lived 3IL Excited State or a 3MLCT/3IL Equilibrium: Efficient Triplet Sensitizers for Low-Power Upconversion.
Shaomin Ji, Wanhua Wu, Wenting Wu, Huimin Guo, Jianzhang Zhao.*
Angew. Chem. Int. Ed., 2011, 50, 1626－1629.
Highlighted by Nature China, 2011, doi:10.1038/nchina.2011.4
http://www.nature.com/nchina/2011/110202/full/nchina.2011.4.html
Highlighted by Chem. Eur. J.
http://onlinelibrary.wiley.com/doi/10.1002/chem.201101102/abstract
43. Chiral Donor Photoinduced-Electron-Transfer (d-PET) Boronic Acid Chemosensors for the Selective Recognition of Tartaric Acids, Disaccharides, and Ginsenosides.
Yubo Wu, Huimin Guo, Xin Zhang, Tony D. James, and Jianzhang Zhao.*
Chem. Eur. J., 2011, 17, 7632 – 7644.
42. Styryl-BODIPY based red-emitting fluorescent OFF–ON molecular probe for specific detection of cysteine.
Jingyin Shao, Huimin Guo, Shaomin Ji, Jianzhang Zhao.*
Biosensors and Bioelectronics, 2011, 26, 3012－3017.
41. Enhanced Enantioselective Recognition with Diastereoisomeric BINOL Based Chiral Fluorescent Boronic Acid Sensors.
Qiuting Li, Huimin Guo,* Yubo Wu, Xin Zhang, Yifan Liu, Jianzhang Zhao.*
J Fluoresc 2011, 21, 2077–2084
40. EnantioselectiveEnantioselective Recognition of Tartaric Acids with Ethynylated Carbazole-Based Chiral Bisboronic Acid Chemosensors with Improved Response at Acidic pH.
Yifan Liu, Xin Zhang, Huimin Guo, Yubo Wu, Qiuting Li, Liping Liu, Jianzhang Zhao.*
J Fluoresc., 2011, 21, 1979–1986.
39. Synthesis of Ethynylated Phenothiazine Based Fluorescent Boronic Acid Probes.
Yubo Wu, Huimin Guo,* Jingyin Shao, Xin Zhang, Shaomin Ji, Jianzhang Zhao.*
J Fluoresc., 2011, 21, 1143–1154.
38. Highly selective fluorescent OFF–ON thiol probes based on dyads of BODIPY and potent intramolecular electron sink 2,4-dinitrobenzenesulfonyl Subunits.
Huimin Guo,* Yingying Jing, Xiaolin Yuan, Shaomin Ji, Jianzhang Zhao,* Xiaohuan Li and Yanyan Kan.
Org. Biomol. Chem., 2011, 9, 3844–3853.
37. Molecular Rotors as Fluorescent Viscosity Sensors: Molecular Design, Polarity Sensitivity, Dipole Moments Changes, Screening Solvents and Deactivation Channel of the Excited States.
Fuke Zhou, Jingyin Shao, Yubin Yang, Jianzhang, Zhao,* Huimin Guo,* Xiaolian Li,* Shaomin Ji, and Zongying Zhang.
Eur. J. Org. Chem., 2011, 4773–4787.
36. Accessing the long-lived emissive 3IL triplet excited states of coumarin fluorophores by direct cyclometallation and its application for oxygen sensing and upconversion.
Wenting Wu, Wanhua Wu, Shaomin Ji, Huimin Guo and Jianzhang Zhao*
Dalton Trans., 2011, 40, 5953–5963.
35. Accessing the long-lived near-IR-emissive triplet excited state in naphthalenediimide with light-harvesting diimine platinum(II) bisacetylide complex and its application for upconversion.
Yifan Liu, Wanhua Wu, Jianzhang Zhao,* Xin Zhang and Huimin Guo*
Dalton Trans., 2011, 2011, 40, 9085–9089 (Inside Front Cover Paper).
34. Coumarin phosphorescence observed with N^N Pt(II) bisacetylide complex and its applications for luminescent oxygen sensing and triplettriplet- annihilation based upconversion.
Haiyang Sun, Huimin Guo,* Wenting Wu, Xin Liu, Jianzhang Zhao*
Dalton Trans., 2011, 40, 7834–7841 (Inside Front Cover Paper).
热点论文(Hot article): http://blogs.rsc.org/dt/2011/06/14/hot-article-coumarin phosphorescence-for-luminescent-oxygen-sensing/
33. Tuning the emission property of carbazole-caped cyclometalated platinum(II) complexes and its application for enhanced luminescent oxygen sensing.
Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Jianzhang Zhao*
Journal of Organometallic Chemistry 2011, 696, 2388–2398.
32. Synthesis of 5,10,15,20-tetraarylporphyrins and Their Platinum(II) Complexes as Luminescent Oxygen Sensing Materials.
Wenting Wu, Wanhua Wu, Shaomin Ji, Huimin Guo, Xin Wang and Jianzhang Zhao.*
Dyes and Pigments, 2011, 89, 199-211
31. Long-lived Emissive Intra-ligand Triplet Excited States (3IL): Next Generation Luminescent Oxygen Sensing Scheme and a Case Study With Red Phosphorescent Diimine Pt(II) Bis(acetylide) Complexes Containing Ethynylated Naphthalimide or Pyrene Subunits.
Huimin Guo,* Shaomin Ji, Wanhua Wu, Wenting Wu, Jingyin Shao, and Jianzhang Zhao.*
Analyst, 2010, 135, 2832–2840.
30.Tuning the Emission Properties of Cyclometalated Platinum(II) Complexes by Intramolecular Electron-Sink/Arylethynylated Ligands and Its Application For Enhanced Luminescent Oxygen Sensing.
Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Peng Song, Keli Han, Lina Chi, Jingyin Shao, and Jianzhang Zhao.*
J. Mater. Chem., 2010, 20, 9775–9786.
29. Naphthalimide Phosphorescence Finally Exposed in a Platinum(II)Diimine Complex.
Huimin Guo, Maria L. Muro-Small, Shaomin Ji, Jianzhang Zhao* and Felix N. Castellano.*
Inorg. Chem., 2010, 49, 6802-6804.
28. Enhanced Luminescence Oxygen Sensing Property of Ru(II) Bispyridine Complexes by Ligand Modification.
Wanhua Wu, S. Ji, W. Wu, H. Guo, X. Wang, Jianzhang Zhao* and Zhonggang Wang.*
Sensors & Actuators: B. Chemical 2010, 149, 395–406.
27. Tuning the Emission Color of Triphenylamine Caped Cyclometalated Platinum(II) Complexes and Its Application for Luminescent Oxygen Sensing and Organic Light Emitting Diode.
Wenting Wu, Chuanhui Cheng, Wanhua Wu, Huimin Guo, Shaomin Ji, Peng Song, Keli Han, Jianzhang Zhao,* Xin Zhang, Yubo Wu and Guotong Du.
Eur. J. Inorg. Chem., 2010, 4683–4696.
26. Observation of Room-temperature Deep-red/Near IR Phosphorescence of Pyrene With Cycloplatinated Complexes: An Experimental and Theoretical Study.
Wenting Wu, Wanhua Wu, Shaomin Ji, Huimin Guo,* and Jianzhang Zhao.*
Eur. J. Inorg. Chem., 2010, 4470–4482.
25. A Highly Selective OFF-ON Red-Emitting Phosphorescent Thiol Probe with Large Stokes Shift and Long Luminescent Lifetime.
Shaomin Ji, Huimin Guo, Xiaolin Yuan, Xiaohuan Li, Haidong Ding, Peng Gao, Chunxia Zhao, Wenting Wu, Wanhua Wu, Jianzhang Zhao.*
Org. Lett. 2010, 12, 2876-2879.
24. Ethynylated Triphenylamine Monoboronic acid Chemosensors: Experimental and Theoretical Studies.
Lina Chi, Yubo Wu, Xin Zhang, Shaomin Ji, Jingyin Shao, Huimin Guo,* Xin Wang, and Jianzhang Zhao.*
J. Fluoresc. 2010, 20, 1255–1265
23. Effect of the Electron Donor/Acceptor Orientation on the Fluorescence Transduction Efficiency of the d-PET Effect of Carbazole-based Fluorescent Boronic Acid Sensors.
Xin Zhang, Yubo Wu, Shaomin Ji, Huimin Guo, Peng Song, Keli Han, Wenting Wu, Wanhua Wu,
Tony D. James, and Jianzhang Zhao.*
J. Org. Chem., 2010, 75, 2578-2588.
22. Synthesis of Polypyridyl Ruthenium Complexes with 2-(1-aryl)-1H-imidazo[4,5-f]-1,10-phenanthroline Ligand and Its Application for Luminescent Oxygen Sensing.
Shaomin Ji, Wanhua Wu, Wenting Wu, Huimin Guo, Xin Zhang, Yubo Wu and Jianzhang Zhao*
Frontiers of Chemistry in China, 2010, 5(2), 193-199. Special issue of Organic Photoswitchable
Multifunctional Molecules and Materials (Edited by Prof. He Tian).
21. Naked-Eye recognition of Cu(II), Zn(II) and Acetate ion by the First Guanine-Based Difunctional Chromoinophore.
K.K. Upadhyay,* Ajit Kumar, Jianzhang Zhao, Rakesh K. Mishra.
Talanta, 2010, in press.
20. Tuning the Luminescence Lifetimes of Ruthenium (II) Polypyridine Complexes and Its Application in Luminescent Oxygen Sensing.
Shaomin Ji, Wanhua Wu, Wenting Wu, Peng Song, Keli Han, Zhonggang Wang, Shasha Liu, Huimin Guo and Jianzhang Zhao.*
J. Mater. Chem., 2010, 20, 1953–1963.
19. Self Assembled Pseudo Double Helix Architecture and Anion Sensing Behavior of a Coumarin Based ICT Probe.
K. K. Upadhyay,* Rakesh K. Mishra, Ajit Kumar, Jianzhang Zhao and Rajendra Prasada.
J. Mol. Struc. 2010, 963(2-3), 228-233.
18. Rational Design of d-PeT Phenylethynylated-Carbazole Monoboronic Acid Fluorescent Sensors for the Selective Detection of alpha-Hydroxyl Carboxylic Acids and Monosaccharides.
Xin Zhang, Lina Chi, Shaomin Ji, Yubo Wu, Peng Song, Keli Han, Huimin Guo, Tony D. James and Jianzhang Zhao.*
J. Am. Chem. Soc. 2009, 131(47), 17452-17463.
17. Synthesis of Novel Bispyrene Diamines and Their Application as Ratiometric Fluorescent Probes for Detection of DNA.
Yubin Yang, Shaomin Ji, Fuke Zhou, Jianzhang Zhao.*
Biosensors and Bioelectronics. 2009, 24, 3442–3447
16. Tuning the Intramolecular charge Transfer of Alkynylpyrenes: Effect on Photophysical Properties and Its Application in Design of OFF-ON Fluorescent Thiol Probes.
Shaomin Ji, Jun Yang, Qing Yang, Shasha Liu, Maodu Chen and Jianzhang Zhao.*
J. Org. Chem. 2009, 74,4855-4865.
15. Real-time Monitoring of Luminescent Lifetime Changes of PtOEP Oxygen Sensing Film with LED/photodiode-based Time-domain Lifetime Device.
Shaomin Ji, Wanhua Wu, Yubo Wu, Taiyang Zhao, Fuke Zhou, Yubin Yang, Xin Zhang, Xiaofen Liang, Wenting Wu, Lina Chi, Zhonggang Wang and Jianzhang Zhao*.
Analyst, 2009, 134, 958-965.
14. 3,6-Disubstituted Carbazole-Based Bisboronic Acids with Unusual Fluorescence Transduction as Enantioselective Fluorescent Chemosensors for Tartaric Acid.
Feng Han, Lina Chi, Xiaofen Liang, Shaomin Ji, Shasha Liu, Fuke Zhou, Yubo Wu, Keli Han, Jianzhang Zhao,* and Tony D. James*.
J. Org. Chem. 2009, 74, 1333-1336.
13. Chiral Mono Boronic Acid As Fluorescent Enantioselective Sensor for Mono alpha-Hydroxyl Carboxylic Acids
Lina Chi, Jianzhang Zhao,* and Tony D. James*
J. Org. Chem. 2008, 73, 4684–4687
12. Colorimetric Fluoride-Anion Sensor Based on Intramolecular Hydrogen Bonding and Enol–Keto Tautomerization of a Phenothiazine Derivative.
Feng Han and Jianzhang Zhao*
Helv. Chim. Acta. 2008, 91, 635-645
11. Environment Sensitive Phenothiazine Dyes Strongly Fluorescence in Protic Solvents.
Feng Han, Lina Chi, Wenting Wu, Xiaofen Liang, Meiyan Fu, Jianzhang Zhao*
Journal of Photochemistry and Photobiology A: Chemistry 2008, 196, 10–23.
10. 6,6'-Bis-substituted BINOL Boronic Acids as Enantioselective and Chemoselective fluorescent chemosensors for D-sorbitol
Xiaofen Liang, Tony D. James, Jianzhang Zhao*
Tetrahedron 2008, 64, 1309-1315.
9. Cis/trans Configurations of the Peptide C-N bonds: Isomerization and Photoswitching.
Jean-Claude Micheau, Jianzhang Zhao*
J. Phys. Org. Chem. 2007, 20(11), 810-820. Review.
8. Simple Bisthiocarbonohydrazones as Sensitive, selective, Colorimetric, and Switch-On Fluorescent Chemosensors for Fluoride Anions.
Feng Han, Yuhui Bao, Zhigang Yang, Thomas M. Fyles, Jianzhang Zhao,* Xiaojun Peng,* Jiangli Fan, Shiguo Sun.
Chem. Eur. J. 2007, 13, 2880–2892.
7. Chemoselective and enantioselective fluorescent recognition of sugar alcohols by a bisboronic acid receptor.
Jianzhang Zhao, Tony D. James.*
J. Mater. Chem., 2005, 15(27-28), 2896-2901.
6. Fluorescence Quenching in a Dual Fluorophore Boronic Acid Receptor Enhances the Chiral Discrimination of the Receptor for Tartaric Acid.
Jianzhang Zhao, Tony D. James.*
Chem. Commun, 2005,1889-1891.
5. An Enantioselective Fluorescent Sensor for Sugar Acids.
Jianzhang Zhao, Matthew G. Davidson, Mary F. Mahon, Gabriele Kociok-Kohn, Tony D. James.*
J.Am.Chem.Soc. 2004,126(49),16179-16186.
4. cis/trans Photoisomerization of Secondary Thiopeptide Bonds.
Jianzhang Zhao,* Jean-Claude Micheau,* Carolyn Vargas, Cordelia Schiene-Fischer.*
Chem. Eur. J. 2004, 10, 6093-6101.
3. Chiral Binol Bisboronic Acid as Fluorescence Sensor for Sugar Acids.
Jianzhang Zhao, Thomas M. Fyles, Tony D. James.*
Angew. Chem. Int. Ed. Engl. 2004, 43(26), 3461-3464.
2. Direct Photomodulation of Peptide Backbone Conformations.
Jianzhang Zhao,* D. Wildemann, M. Jakob, C. Vargas, C. Schiene-Fischer.*
Chem. Commun. 2003,2810-2811.
1. Cucurbit[n]uril Derivatives Soluble in Water and Organic Solvents.
Jianzhang Zhao, Hee-Joon Kim, Jinho Oh, Soo-Young Kim, Jae Wook Lee, Shigeru Sakamoto, Kentaro Yamaguchi, Kimoon Kim.*
Angew. Chem. Int. Ed. Engl. 2001, 40(22), 4233-4235.
工作成果（奖励、专利等）
所培养的学生多人次获得各种奖励，比如，教育部博士生学术新人奖（籍少敏，2010年）； 辽宁省自然科学学术成果特等奖（学术论文类，2011年，籍少敏）；辽宁省自然科学学术成果一等奖（学术论文类， 2011年，张欣）；大连市自然科学优秀学术论文特等奖（2011年，籍少敏）；辽宁省优秀毕业生（3人次）；大连理工大学优秀研究生（20人次）；大连理工大学中凯化学奖学金（2人次）、大连理工大学昭和电工奖学金（2人次）；大连理工大学赢创奖学金（3人次），等等。
在读学生人数
15
毕业学生人数
6